In the given electrochemical cell, $Ag_{(s)} | AgCl_{(s)} | Cl^-_{(aq)}, Fe^{2+}_{(aq)}, Fe^{3+}_{(aq)} | Pt_{(s)}$ at $298 \ K$, the cell potential $(E_{cell})$ will increase when :
$(A)$ Concentration of $Fe^{2+}$ is increased.
$(B)$ Concentration of $Fe^{3+}$ is decreased.
$(C)$ Concentration of $Fe^{2+}$ is decreased.
$(D)$ Concentration of $Fe^{3+}$ is increased.
$(E)$ Concentration of $Cl^-$ is increased.
Choose the correct answer from the options given below :
$(A)$ Concentration of $Fe^{2+}$ is increased.
$(B)$ Concentration of $Fe^{3+}$ is decreased.
$(C)$ Concentration of $Fe^{2+}$ is decreased.
$(D)$ Concentration of $Fe^{3+}$ is increased.
$(E)$ Concentration of $Cl^-$ is increased.
Choose the correct answer from the options given below :
- A$A$ and $B$ only
- B$A$ and $E$ only
- C$B$ only
- D$C, D$ and $E$ only
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$Cu_{(s)} + Sn^{2+}(0.001 \ M) \rightarrow Cu^{2+}(0.01 \ M) + Sn_{(s)}$
The Gibbs free energy change for the above reaction at $298 \ K$ is $x \times 10^{-1} \ kJ \ mol^{-1}$;
The value of $x$ is ..... [nearest integer] $\left[\text{Given}: E^{\ominus}_{Cu^{2+}/Cu} = 0.34 \ V; E^{\ominus}_{Sn^{2+}/Sn} = -0.14 \ V; F = 96500 \ C \ mol^{-1}\right]$
The Gibbs free energy change for the above reaction at $298 \ K$ is $x \times 10^{-1} \ kJ \ mol^{-1}$;
The value of $x$ is ..... [nearest integer] $\left[\text{Given}: E^{\ominus}_{Cu^{2+}/Cu} = 0.34 \ V; E^{\ominus}_{Sn^{2+}/Sn} = -0.14 \ V; F = 96500 \ C \ mol^{-1}\right]$
DifficultJEE MAIN 2022
View SolutionIf a cell has a standard electrode potential of $0.295 \ V$ and $n = 2$,calculate its equilibrium constant at $298 \ K$.
Medium
View SolutionCalculate the $EMF$ of the cell: $Cr | Cr^{+3}(0.1 \, M) || Fe^{+2}(0.01 \, M) | Fe$
(Given: $E^o_{Cr^{+3}|Cr} = -0.75 \, V$,$E^o_{Fe^{+2}|Fe} = -0.45 \, V$) (in $, V$)
(Given: $E^o_{Cr^{+3}|Cr} = -0.75 \, V$,$E^o_{Fe^{+2}|Fe} = -0.45 \, V$) (in $, V$)
Difficult
View SolutionConsider the cell:
$Pt_{(s)} | H_{2(g)}(1 \ atm) | H^{+}_{(aq)}, [H^{+}]=1 \ M || Fe^{3+}_{(aq)}, Fe^{2+}_{(aq)} | Pt_{(s)}$
Given: $E^0_{Fe^{3+}/Fe^{2+}} = 0.771 \ V$ and $E^0_{H^{+}/\frac{1}{2}H_2} = 0 \ V$ at $T = 298 \ K$.
If the potential of the cell is $0.712 \ V$,the ratio of concentration of $Fe^{2+}$ to $Fe^{3+}$ is $........$. (Nearest integer)
$Pt_{(s)} | H_{2(g)}(1 \ atm) | H^{+}_{(aq)}, [H^{+}]=1 \ M || Fe^{3+}_{(aq)}, Fe^{2+}_{(aq)} | Pt_{(s)}$
Given: $E^0_{Fe^{3+}/Fe^{2+}} = 0.771 \ V$ and $E^0_{H^{+}/\frac{1}{2}H_2} = 0 \ V$ at $T = 298 \ K$.
If the potential of the cell is $0.712 \ V$,the ratio of concentration of $Fe^{2+}$ to $Fe^{3+}$ is $........$. (Nearest integer)
$Pt_{(s)} | H_{2(g)}(1 \ bar) | H^{+}_{(aq)}(1 \ M) || M^{3+}_{(aq)}, M^{+}_{(aq)} | Pt_{(s)}$
The $E_{cell}$ for the given cell is $0.1115 \ V$ at $298 \ K$ when $\frac{[M^{+}_{(aq)}]}{[M^{3+}_{(aq)}]} = 10^{a}$.
The value of $a$ is.
Given : $E^{\circ}_{M^{3+}/M^{+}} = 0.2 \ V$
$\frac{2.303 \ RT}{F} = 0.059 \ V$
The $E_{cell}$ for the given cell is $0.1115 \ V$ at $298 \ K$ when $\frac{[M^{+}_{(aq)}]}{[M^{3+}_{(aq)}]} = 10^{a}$.
The value of $a$ is.
Given : $E^{\circ}_{M^{3+}/M^{+}} = 0.2 \ V$
$\frac{2.303 \ RT}{F} = 0.059 \ V$
DifficultJEE MAIN 2023
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