In the reaction $I_2 + 2S_2O_3^{2-} \to 2I^{-} + S_4O_6^{2-}$,the equivalent weight of iodine will be equal to

Which of the following will not change the orange colour of $K_2Cr_2O_7$ into green colour in an acidic medium?

Match List-$I$ with the List-$II$.

List-$I$ (Reaction)	List-$II$ (Type of redox reaction)
$A$. $N_{2(g)} + O_{2(g)} \rightarrow 2 NO_{(g)}$	$I$. Decomposition
$B$. $2 Pb(NO_3)_{2(s)} \rightarrow 2 PbO_{(s)} + 4 NO_{2(g)} + O_{2(g)}$	$II$. Displacement
$C$. $2 Na_{(s)} + 2 H_2 O_{(l)} \rightarrow 2 NaOH_{(aq)} + H_{2(g)}$	$III$. Disproportionation
$D$. $2 NO_{2(g)} + 2 OH^-_{(aq)} \rightarrow NO^-_{2(aq)} + NO^-_{3(aq)} + H_2 O_{(l)}$	$IV$. Combination

Choose the correct answer from the options given below:

How do you account for the following observations?
$(a)$ Though alkaline potassium permanganate and acidic potassium permanganate both are used as oxidants,yet in the manufacture of benzoic acid from toluene,we use alcoholic potassium permanganate as an oxidant. Why? Write a balanced redox equation for the reaction.
$(b)$ When concentrated sulphuric acid is added to an inorganic mixture containing chloride,we get a colourless pungent-smelling gas $HCl$,but if the mixture contains bromide,then we get red vapour of bromine. Why?

$200 \ mL$ of $x \times 10^{-3} \ M$ potassium dichromate $(K_2Cr_2O_7)$ is required to oxidise $750 \ mL$ of $0.6 \ M$ Mohr's salt $(FeSO_4 \cdot (NH_4)_2SO_4 \cdot 6H_2O)$ solution in acidic medium. Here $x =$ ?

Which of the following is not correct?