In the wet tests for identification of various cations by precipitation,which transition element cation does not belong to group $IV$ in qualitative inorganic analysis?

An aqueous solution of a salt $X$ turns blood red on treatment with $CNS^{-}$ and blue on treatment with $K_4[Fe(CN)_6]$. $X$ also gives a positive chromyl chloride test. The salt $X$ is

The group reagent for analytical group $IV$ is:

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$(NH_4)_2SO_4 + Sr(OH)_2 \longrightarrow SrSO_4 \downarrow + 2NH_3 \uparrow + 2H_2O$

To an aqueous solution containing ions such as $Al^{3+}, Zn^{2+}, Ca^{2+}, Fe^{3+}, Ni^{2+}, Ba^{2+}$ and $Cu^{2+}$,concentrated $HCl$ was added,followed by $H_{2}S$. The total number of cations precipitated during this reaction is/are:

Mark the compound which turns black with $NH_4OH$.