In which solution,solute is liquid and solvent is gas?

Which one of the following statements is false?

$2 \ \text{moles}$ each of ethylene glycol and glucose are dissolved in $500 \ \text{g}$ of water. The boiling point of the resulting solution is $:$ (Given $:$ Ebullioscopic constant of water $= 0.52 \ \text{K kg mol}^{-1}$) (in $\text{K}$)

What is boiling point? What is freezing point?

Which of the following statements are not correct?
$A$. For water, magnitude of $K_b$ is more than the magnitude of $K_f$.
$B$. The elevation in boiling point of water when a non-volatile solute is added to it is larger in magnitude than its depression in freezing point.
$C$. Osmotic pressure measurement is preferred over any other colligative property to determine molar mass of proteins and polymers.
$D$. The dimerised form of benzoic acid in benzene is $C_6H_5 - C(=O) - OH \cdots O = C(OH) - C_6H_5$. Choose the correct answer from the options given below:

Column-$I$ (Various solutions)	Column-$II$ (Their freezing point)
$a$. $0.1 \ M \ BaCl_2$ solution	$p$. $271 \ K$
$b$. $0.1 \ M \ NaCl$ solution	$q$. $270 \ K$
$c$. $0.1 \ M \ K_3[Fe(CN)_6]$ solution	$s$. $269 \ K$
$d$. $0.1 \ M \ Al_2(SO_4)_3$ solution	$r$. $268 \ K$

Given: Freezing point of $0.1 \ M$ sucrose solution $= 272 \ K$ and Freezing point of water $= 273 \ K$. Assume molarity $=$ molality. Which of the following options shows the correct matches?