Which of the following is an incorrect match?

  • A
    Benzene $\xrightarrow[AlCl_3 \text{ (Anhy.)}]{CH_3Cl}$ Friedel-Crafts reaction
  • B
    Benzene $+ HCN + HCl \xrightarrow{AlCl_3 \text{ (Anhy.)}}$ Gattermann aldehyde synthesis
  • C
    Benzene $+ CHCl_3 \xrightarrow{AlCl_3 \text{ (Anhy.)}}$ Reimer-Tiemann reaction
  • D
    $CH_3-Br + AgF \xrightarrow{\Delta}$ Swarts reaction

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Which of the following is least reactive towards nucleophilic substitution reaction?

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$2-$Bromobutane on heating with alcoholic $KOH$ forms

$2-$chloro$-2-$methylpentane on reaction with sodium methoxide in methanol yields:
$(1)\ C_2H_5-CH_2-C(CH_3)_2-OCH_3$
$(2)\ C_2H_5-CH_2-C(CH_3)=CH_2$
$(3)\ C_2H_5-CH=C(CH_3)_2$

Which of the following undergoes $S_{N^{1}}$ reaction?

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