Monochlorination of toluene in the presence o | vedclass

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(D) Halogenation in the presence of light follows a free radical pathway and reacts with the alkyl group to give a haloalkyl compound.The formed haloa

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benzyl alcohol

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(D) Halogenation in the presence of light follows a free radical pathway and reacts with the alkyl group to give a haloalkyl compound.The formed haloalkyl,in the presence of an alkaline medium,undergoes a nucleophilic substitution reaction where the halogen atom is replaced by a hydroxyl group to form an alcohol.The reaction with toluene can be represented as:$C_6H_5CH_3$ $\xrightarrow{Cl_2, hv} C_6H_5CH_2Cl$ $\xrightarrow{	ext{aq. } NaOH} C_6H_5CH_2OH$Thus,the monochlorination of toluene in sunlight followed by hydrolysis with aqueous $NaOH$ yields benzyl alcohol.

Monochlorination of toluene in the presence of sunlight followed by hydrolysis gives:

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