Nitrogen has positive electron gain enthalpy whereas oxygen has negative. However,oxygen has lower ionisation enthalpy than nitrogen. Explain.

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(N/A) The electronic configuration of ${}_{7}N$ is $1s^{2}, 2s^{2}, 2p^{3}$. Nitrogen has a stable half-filled $p$-orbital configuration,which makes the addition of an extra electron unfavorable,resulting in a positive electron gain enthalpy.
The electronic configuration of ${}_{8}O$ is $1s^{2}, 2s^{2}, 2p^{4}$. Adding an electron to oxygen leads to a more stable half-filled $p$-orbital $(2p^{3})$,making the process exothermic (negative electron gain enthalpy).
Regarding ionisation enthalpy,oxygen $(1s^{2}, 2s^{2}, 2p^{4})$ has a lower value than nitrogen $(1s^{2}, 2s^{2}, 2p^{3})$ because removing an electron from oxygen results in a stable half-filled $2p^{3}$ configuration. Conversely,nitrogen has a stable half-filled configuration,making the removal of an electron more difficult.

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Similar Questions

Which of the following statements are $NOT$ true about the periodic table?
$A.$ The properties of elements are a function of atomic weights.
$B.$ The properties of elements are a function of atomic numbers.
$C.$ Elements having similar outer electronic configuration are arranged in the same period.
$D.$ An element's location reflects the quantum numbers of the last filled orbital.
$E.$ The number of elements in a period is the same as the number of atomic orbitals available in the energy level that is being filled.
Choose the correct answer from the options given below:

Choose the correct option regarding the following statements:
Statement-$1$: Nitrogen has lesser electron gain enthalpy than oxygen.
Statement-$2$: Oxygen has lesser ionization enthalpy than nitrogen.

Which one of the following sets of ions represents the collection of isoelectronic species?

Which of the following orders is correct according to the given property?

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The set of elements that differ in mutual relationship from those of the other sets is:

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