Reduction of the metal centre in aqueous permanganate ion involves

In which of the following reactions does the oxidation number not change?

If zinc pieces are added to yellow $FeCl_3$ solution,it turns to very light green. It is because

Which of the following reactions are correct? (Ignore balancing of the reactions)
$(I)$ $Al + NaOH \xrightarrow{\Delta} NaAlO_2 + H_2$
$(II)$ $P_4 + NaOH + H_2O \to NaH_2PO_2 + PH_3$
$(III)$ $S + NaOH \to Na_2S_2O_3 + Na_2S + H_2O$

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$CaSO_3(s) + H_2SO_4(aq) \longrightarrow CaSO_4(s) + SO_2(g) + H_2O(l)$

$100 \ mL$ of $0.1 \ M$ $Fe^{2+}$ solution was titrated with $\frac{1}{60} \ M$ $Cr_2O_7^{2-}$ solution in acid medium. What is the volume (in $L$) of $Cr_2O_7^{2-}$ solution consumed?