The same gas is filled in two vessels of the same volume at the same temperature. If the ratio of the number of molecules is $1:4$,then:
$A.$ The $r.m.s.$ velocity of gas molecules in the two vessels will be the same.
$B.$ The ratio of pressure in these vessels will be $1:4$.
$C.$ The ratio of pressure will be $1:1$.
$D.$ The $r.m.s.$ velocity of gas molecules in the two vessels will be in the ratio of $1:4$.

  • A
    $A$ and $C$ only
  • B
    $B$ and $D$ only
  • C
    $A$ and $B$ only
  • D
    $C$ and $D$ only

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According to the kinetic theory of gases,which of the following statements is $WRONG$?

As shown schematically in the figure,two vessels contain water solutions (at temperature $T$) of potassium permanganate $(KMnO_4)$ of different concentrations $n_1$ and $n_2$ $(n_1 > n_2)$ molecules per unit volume with $\Delta n = (n_1 - n_2) \ll n_1$. When they are connected by a tube of small length $\ell$ and cross-sectional area $S$,$KMnO_4$ starts to diffuse from the left to the right vessel through the tube. Consider the collection of molecules to behave as dilute ideal gases and the difference in their partial pressure in the two vessels causing the diffusion. The speed $v$ of the molecules is limited by the viscous force $-\beta v$ on each molecule,where $\beta$ is a constant. Neglecting all terms of the order $(\Delta n)^2$,which of the following is/are correct? ($k_B$ is the Boltzmann constant)
$(A)$ the force causing the molecules to move across the tube is $\Delta n k_B T S$
$(B)$ force balance implies $n_1 \beta v \ell = \Delta n k_B T$
$(C)$ total number of molecules going across the tube per sec is $\left(\frac{\Delta n}{\ell}\right)\left(\frac{k_B T}{\beta}\right) S$
$(D)$ rate of molecules getting transferred through the tube does not change with time

One mole of an ideal diatomic gas is taken through the cycle as shown in the figure.
$1 \rightarrow 2$: isochoric process
$2 \rightarrow 3$: straight line on $P-V$ diagram
$3 \rightarrow 1$: isobaric process
The average molecular speed of the gas in the states $1, 2$ and $3$ are in the ratio

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Which one of the following gases possesses the largest internal energy?

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The figure shows a plot of $PV/T$ versus $P$ for $1.00 \times 10^{-3} \; kg$ of oxygen gas at two different temperatures.
$(a)$ What does the dotted plot signify?
$(b)$ Which is true: $T_{1} > T_{2}$ or $T_{1} < T_{2}$?
$(c)$ What is the value of $PV/T$ where the curves meet on the $y$-axis?
$(d)$ If we obtained similar plots for $1.00 \times 10^{-3} \; kg$ of hydrogen,would we get the same value of $PV/T$ at the point where the curves meet on the $y$-axis? If not,what mass of hydrogen yields the same value of $PV/T$ (for the low-pressure,high-temperature region of the plot)?
(Molecular mass of $H_{2} = 2.02 \; u$,of $O_{2} = 32.0 \; u$,$R = 8.31 \; J \; mol^{-1} K^{-1}$.)

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