Some reactions of amines are given. Which one | vedclass

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(D) The reaction of secondary aliphatic amines with nitrous acid $(HNO_2)$ produces $N$-nitrosamines,which are yellow oily compounds. The reaction is:

Vedclass · Accepted Answer

$(CH_3)_2NH + NaNO_2 + HCl \rightarrow (CH_3)_2N-N=O + NaCl + H_2O$

Vedclass · Answer

(D) The reaction of secondary aliphatic amines with nitrous acid $(HNO_2)$ produces $N$-nitrosamines,which are yellow oily compounds. The reaction is: $(CH_3)_2NH + HNO_2 \rightarrow (CH_3)_2N-N=O + H_2O$. Option $D$ is incorrect because the reaction of dimethylamine with nitrous acid (generated from $NaNO_2 + HCl$) forms $N$-nitrosodimethylamine,not the structure implied by the notation in the option. Furthermore,the reaction shown in the option is chemically inaccurate regarding the products and stoichiometry for the given reactants.

Some reactions of amines are given. Which one is not correct?

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