The $e.m.f.$ of the following galvanic cells are represented by $E_1, E_2, E_3$ and $E_4$. Which of the following statements is true?
$(i)$ $Zn|Zn^{2+} (1 \, M)||Cu^{2+} (1 \, M)|Cu$
$(ii)$ $Zn|Zn^{2+} (0.1 \, M)||Cu^{2+} (1 \, M)|Cu$
$(iii)$ $Zn|Zn^{2+} (1 \, M)||Cu^{2+} (0.1 \, M)|Cu$
$(iv)$ $Zn|Zn^{2+} (0.1 \, M)||Cu^{2+} (0.1 \, M)|Cu$
$(i)$ $Zn|Zn^{2+} (1 \, M)||Cu^{2+} (1 \, M)|Cu$
$(ii)$ $Zn|Zn^{2+} (0.1 \, M)||Cu^{2+} (1 \, M)|Cu$
$(iii)$ $Zn|Zn^{2+} (1 \, M)||Cu^{2+} (0.1 \, M)|Cu$
$(iv)$ $Zn|Zn^{2+} (0.1 \, M)||Cu^{2+} (0.1 \, M)|Cu$
- A$E_1 > E_2 > E_3 > E_4$
- B$E_3 > E_2 > E_1 > E_4$
- C$E_3 > E_1 = E_4 > E_2$
- D$E_2 > E_1 = E_4 > E_3$
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For a general redox reaction: $aA + bB \xrightarrow{n e^-} cC + dD$. Derive the Nernst equation.
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View SolutionFor the following electrochemical cell at $298 \ K$,
$Pt_{(s)} \mid H_2(g, 1 \ bar) \mid H^{+}(aq, 1 \ M) \parallel M^{4+}_{(aq)}, M^{2+}_{(aq)} \mid Pt_{(s)}$
$E_{\text{cell}} = 0.092 \ V$ when $\frac{[M^{2+}_{(aq)}]}{[M^{4+}_{(aq)}]} = 10^x$
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The value of $x$ is
$Pt_{(s)} \mid H_2(g, 1 \ bar) \mid H^{+}(aq, 1 \ M) \parallel M^{4+}_{(aq)}, M^{2+}_{(aq)} \mid Pt_{(s)}$
$E_{\text{cell}} = 0.092 \ V$ when $\frac{[M^{2+}_{(aq)}]}{[M^{4+}_{(aq)}]} = 10^x$
Given : $E^0_{M^{4+}/M^{2+}} = 0.151 \ V$; $2.303 \frac{RT}{F} = 0.059 \ V$
The value of $x$ is
The $emf$ of the following cell $Mg|Mg^{2+}(0.01 \ M)||Sn^{2+}(0.1 \ M)|Sn$ at $298 \ K$ in $V$ is: (Given: $E^{\circ}_{Mg^{2+}|Mg} = -2.34 \ V, E^{\circ}_{Sn^{2+}|Sn} = -0.14 \ V$)
$Cu_{(s)} + Sn^{2+}(0.001 \ M) \rightarrow Cu^{2+}(0.01 \ M) + Sn_{(s)}$
The Gibbs free energy change for the above reaction at $298 \ K$ is $x \times 10^{-1} \ kJ \ mol^{-1}$;
The value of $x$ is ..... [nearest integer] $\left[\text{Given}: E^{\ominus}_{Cu^{2+}/Cu} = 0.34 \ V; E^{\ominus}_{Sn^{2+}/Sn} = -0.14 \ V; F = 96500 \ C \ mol^{-1}\right]$
The Gibbs free energy change for the above reaction at $298 \ K$ is $x \times 10^{-1} \ kJ \ mol^{-1}$;
The value of $x$ is ..... [nearest integer] $\left[\text{Given}: E^{\ominus}_{Cu^{2+}/Cu} = 0.34 \ V; E^{\ominus}_{Sn^{2+}/Sn} = -0.14 \ V; F = 96500 \ C \ mol^{-1}\right]$
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View SolutionConsider the following cell reaction:
$2 Fe_{(s)} + O_{2_{(g)}} + 4 H_{(aq)}^{+} \rightarrow 2 Fe_{(aq)}^{2+} + 2 H_2O_{(l)} \quad E^{\circ} = 1.67 \ V$. At $[Fe^{2+}] = 10^{-3} \ M, P(O_2) = 0.1 \ atm$ and $pH = 3$,the cell potential at $25^{\circ} C$ is (in $V$)
$2 Fe_{(s)} + O_{2_{(g)}} + 4 H_{(aq)}^{+} \rightarrow 2 Fe_{(aq)}^{2+} + 2 H_2O_{(l)} \quad E^{\circ} = 1.67 \ V$. At $[Fe^{2+}] = 10^{-3} \ M, P(O_2) = 0.1 \ atm$ and $pH = 3$,the cell potential at $25^{\circ} C$ is (in $V$)
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