The aqueous solution of which of the following complexes has the least conductivity under identical conditions?

  • A
    $[Cr(H_2O)_6]Cl_3$
  • B
    $[Cr(H_2O)_4Cl_2]Cl \cdot 2H_2O$
  • C
    $[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O$
  • D
    $[Cr(H_2O)_3Cl_3]$

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$CrCl_3 \cdot xNH_3$ can exist as a complex. $A$ $0.1 \ m$ aqueous solution of this complex shows a depression in freezing point of $0.558^{\circ} C$. Assuming $100 \%$ ionisation of this complex and that the coordination number of $Cr$ is $6$,the complex will be: (Given $K_f = 1.86 \ K \ kg \ mol^{-1}$)

Based on the given stability constants (hypothetical values),predict which is the strongest ligand?

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