The conductivity of $0.01 \ M$ aqueous acetic acid measured with a conductivity cell of cell constant $0.5 \ cm^{-1}$ at $298 \ K$ is $3.12 \times 10^{-4} \ S$. If the limiting molar conductivities of $H^{+}$ and $CH_3COO^{-}$ at the same temperature are $349$ and $41 \ S \ cm^2 \ mol^{-1}$ respectively,the dissociation constant of acetic acid is
- A$1.67 \times 10^{-4}$
- B$1.67 \times 10^{-5}$
- C$1.67 \times 10^{-3}$
- D$1.67 \times 10^{-6}$
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Consider the following cell reaction:
$Cd_{(s)} + Hg_{2}SO_{4(s)} + \frac{9}{5}H_{2}O_{(l)} \rightleftharpoons CdSO_{4} \cdot \frac{9}{5}H_{2}O_{(s)} + 2Hg_{(l)}$
The value of $E_{\text{cell}}^{0}$ is $4.315 \ V$ at $25^{\circ}C$. If $\Delta H^{\circ} = -825.2 \ kJ \ mol^{-1}$,the standard entropy change $\Delta S^{\circ}$ in $J \ K^{-1} \ mol^{-1}$ is ........ . (Nearest integer) [Given: Faraday constant $= 96487 \ C \ mol^{-1}$]
$Cd_{(s)} + Hg_{2}SO_{4(s)} + \frac{9}{5}H_{2}O_{(l)} \rightleftharpoons CdSO_{4} \cdot \frac{9}{5}H_{2}O_{(s)} + 2Hg_{(l)}$
The value of $E_{\text{cell}}^{0}$ is $4.315 \ V$ at $25^{\circ}C$. If $\Delta H^{\circ} = -825.2 \ kJ \ mol^{-1}$,the standard entropy change $\Delta S^{\circ}$ in $J \ K^{-1} \ mol^{-1}$ is ........ . (Nearest integer) [Given: Faraday constant $= 96487 \ C \ mol^{-1}$]
Solutions $A$,$B$,and $C$ of the same strong electrolyte offered resistances of $50 \ \Omega$,$100 \ \Omega$,and $150 \ \Omega$ in a given conductivity cell. The resistance observed if they are mixed in a volume proportion which is the reciprocal of their resistances and tested in the same conductivity cell would be ............. $\Omega$.
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View SolutionThe molar conductivity of acetic acid solution at infinite dilution is $390 \ S \ cm^2 \ mol^{-1}$. What is the molar conductivity of $0.01 \ M$ acetic acid solution (in $S \ cm^2 \ mol^{-1}$)? (Given: $K_{a}(CH_3COOH) = 1.8 \times 10^{-5}$,assume $1-\alpha \approx 1$)
Given below are two statements:
Statement $I$: For $KI$,molar conductivity increases steeply with dilution.
Statement $II$: For carbonic acid,molar conductivity increases slowly with dilution.
In the light of the above statements,choose the correct answer from the options given below:
Statement $I$: For $KI$,molar conductivity increases steeply with dilution.
Statement $II$: For carbonic acid,molar conductivity increases slowly with dilution.
In the light of the above statements,choose the correct answer from the options given below:
During the electrolysis of concentrated $H_2SO_4$,perdisulphuric acid $(H_2S_2O_8)$ and $O_2$ are formed at the anode in equimolar amounts. The moles of $H_2$ that will form simultaneously at the other electrode will be (Given: $2H_2SO_4 \rightarrow H_2S_2O_8 + 2H^+ + 2e^-$)
Medium
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