The enthalpy change $(\Delta H)$ for the reaction $N_{2(g)} + 3H_{2(g)} \to 2NH_{3(g)}$ is $-92.38 \ kJ$ at $298 \ K$. The internal energy change $\Delta U$ at $298 \ K$ is $...... \ kJ$.

For the electrochemical cell, $Mg ( s )\left| Mg ^{2+}( aq , 1 M ) \| Cu ^{2+}( aq , 1 M )\right| Cu ( s )$ the standard emf of the cell is $2.70 V$ at $300 K$. When the concentration of $Mg ^{2+}$ is changed to $x M$, the cell potential changes to $2.67 V$ at $300 K$. The value of $x$ is.

(given, $\frac{ F }{ R }=11500 K V ^{-1}$, where $F$ is the Faraday constant and $R$ is the gas constant, The value of $\ln (10)=2.30$ )