The enthalpy change $(\Delta H)$ for the process $N_2H_{4(g)} \to 2N_{(g)} + 4H_{(g)}$ is $1724 \ kJ \ mol^{-1}$. If the bond energy of $N-H$ bond in ammonia is $391 \ kJ \ mol^{-1}$,what is the bond energy of $N-N$ bond in $N_2H_4$ in $kJ \ mol^{-1}$?

  • A
    $160$
  • B
    $391$
  • C
    $1173$
  • D
    $320$

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The heat of transition $(\Delta H_t)$ of graphite into diamond would be,where
$C(\text{graphite}) + O_{2(g)} \to CO_{2(g)}; \Delta H = x \ kJ \ mol^{-1}$
$C(\text{diamond}) + O_{2(g)} \to CO_{2(g)}; \Delta H = y \ kJ \ mol^{-1}$

If the combustion of $1 \ g$ of graphite produces $20.7 \ kJ$ of heat,what will be the molar enthalpy change? Give the significance of the sign also.

Given:
$2C + 2O_2 \to 2CO_2 : \Delta H = -787 \text{ kJ}$
$H_2 + \frac{1}{2}O_2 \to H_2O : \Delta H = -286 \text{ kJ}$
$C_2H_2 + \frac{5}{2}O_2 \to 2CO_2 + H_2O : \Delta H = -1310 \text{ kJ}$
Calculate the heat of formation of acetylene $(C_2H_2)$ in $\text{kJ}$.

The bond dissociation enthalpy of $X_2$,$\Delta H_{\text{bond}}^{\circ}$,calculated from the given data is $...$ $kJ \ mol^{-1}$. (Nearest integer)
$M^{+}X^{-}_{(s)} \rightarrow M^{+}_{(g)} + X^{-}_{(g)} \quad \Delta H_{\text{lattice}}^{\circ} = 800 \ kJ \ mol^{-1}$
$M_{(s)} \rightarrow M_{(g)} \quad \Delta H_{\text{sub}}^{\circ} = 100 \ kJ \ mol^{-1}$
$M_{(g)} \rightarrow M^{+}_{(g)} + e^{-}_{(g)} \quad \Delta H_{i}^{\circ} = 500 \ kJ \ mol^{-1}$
$X_{(g)} + e^{-}_{(g)} \rightarrow X^{-}_{(g)} \quad \Delta H_{\text{eg}}^{\circ} = -300 \ kJ \ mol^{-1}$
$M_{(s)} + \frac{1}{2}X_{2(g)} \rightarrow M^{+}X^{-}_{(s)} \quad \Delta H_{f}^{\circ} = -400 \ kJ \ mol^{-1}$
[Given : $M^{+}X^{-}$ is a pure ionic compound and $X$ forms a diatomic molecule $X_2$ in gaseous state]

What will be the $C-H$ bond enthalpy if:
$CH_{4(g)} + 2O_{2(g)} \rightarrow CO_{2(g)} + 2H_2O_{(l)};$ $\Delta H = -890 \, kJ$
$CO_{2(g)} \rightarrow C_{(graphite)} + O_{2(g)};$ $\Delta H = 393 \, kJ$
$2H_2O_{(l)} \rightarrow 2H_{2(g)} + O_{2(g)};$ $\Delta H = 571 \, kJ$
$2H_{2(g)} \rightarrow 4H_{(g)};$ $\Delta H = 871 \, kJ$
$C_{(graphite)} \rightarrow C_{(g)};$ $\Delta H = 716 \, kJ$

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