The following reaction takes place at $298 \, K$ in an electrochemical cell involving two metals $A$ and $B$,
$A^{2+}_{(aq)} + B_{(s)} \rightarrow B^{2+}_{(aq)} + A_{(s)}$
with $[A^{2+}] = 4 \times 10^{-3} \, M$ and $[B^{2+}] = 2 \times 10^{-3} \, M$ in the respective half-cells,the cell $EMF$ is $1.091 \, V$.
The equilibrium constant of the reaction is closest to

  • A
    $4 \times 10^{36}$
  • B
    $2 \times 10^{37}$
  • C
    $2 \times 10^{34}$
  • D
    $4 \times 10^{37}$

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In the given electrochemical cell, $Ag_{(s)} | AgCl_{(s)} | Cl^-_{(aq)}, Fe^{2+}_{(aq)}, Fe^{3+}_{(aq)} | Pt_{(s)}$ at $298 \ K$, the cell potential $(E_{cell})$ will increase when :
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$(B)$ Concentration of $Fe^{3+}$ is decreased.
$(C)$ Concentration of $Fe^{2+}$ is decreased.
$(D)$ Concentration of $Fe^{3+}$ is increased.
$(E)$ Concentration of $Cl^-$ is increased.
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