The given data are for the reaction:
$2NO_{(g)} + Cl_{2(g)} \to 2NOCl_{(g)}$ at $298 \ K$
Experiment$[Cl_2] \ (M)$$[NO] \ (M)$Rate $(mol \ L^{-1} \sec^{-1})$
$I$$0.05$$0.05$$1 \times 10^{-3}$
$II$$0.15$$0.05$$3 \times 10^{-3}$
$III$$0.05$$0.15$$9 \times 10^{-3}$

The rate law for the reaction is:

  • A
    $r = k[NO][Cl_2]$
  • B
    $r = k[Cl_2][NO]^2$
  • C
    $r = k[Cl_2]^2[NO]$
  • D
    $r = k[Cl_2]$

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Similar Questions

Consider the reaction:
$Cl_{2(aq)} + H_2S_{(aq)} \rightarrow S_{(s)} + 2H^{+}_{(aq)} + 2Cl^{-}_{(aq)}$
The rate equation for this reaction is:
$\text{rate} = k[Cl_2][H_2S]$
Which of these mechanisms is/are consistent with this rate equation?
$A.$ $Cl_2 + H_2S \rightarrow H^{+} + Cl^{-} + Cl^{+} + HS^{-}$ (slow)
$Cl^{+} + HS^{-} \rightarrow H^{+} + Cl^{-} + S$ (fast)
$B.$ $H_2S \rightleftharpoons H^{+} + HS^{-}$ (fast equilibrium)
$Cl_2 + HS^{-} \rightarrow 2Cl^{-} + H^{+} + S$ (slow)

In the reaction sequence $A$ $\xrightarrow{K_1} B$ $\xrightarrow{K_2} C$ $\xrightarrow{K_3} D$,where $K_3 > K_2 > K_1$,which step determines the rate of the reaction?

For the gaseous reaction,$N_2O_5 \rightarrow 2NO_2 + \frac{1}{2}O_2$,the rate can be expressed as:
$-\frac{d[N_2O_5]}{dt} = K_1[N_2O_5]$
$+\frac{d[NO_2]}{dt} = K_2[N_2O_5]$
$+\frac{d[O_2]}{dt} = K_3[N_2O_5]$
The correct relation between $K_1, K_2$ and $K_3$ is:

The rate of reaction,$A + B + C \longrightarrow P$ is given by
$r = K[A]^{1/2} [B]^{1/2} [C]^{1/4}$
The order of reaction is

Identify the order of reaction if its rate constant is $x \ sec^{-1}$.

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