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Molecular weight of an organic acid is given by

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Complete reaction of $2.0 \, g$ of calcium (at. wt. $= 40$) with excess $HCl$ produces $1.125 \, L$ of $H_2$ gas. Complete reaction of the same quantity of another metal $M$ with excess $HCl$ produces $1.85 \, L$ of $H_2$ gas under identical conditions. The equivalent weight of $M$ is closest to

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