The major products $P$ and $Q$ formed in the following reactions of benzonitrile are

  • A
    Benzamide and Benzylamine
  • B
    Benzaldimine and Aniline
  • C
    Benzylamine and Aniline
  • D
    Aniline and Benzamide

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Match each of the compounds in Column $I$ with its characteristic reaction$(s)$ in Column $II$.
Column $I$ Column $II$
$A$. $CH_3CH_2CH_2CN$ $p$. Reduction with $Pd-C/H_2$
$B$. $CH_3CH_2OCOCH_3$ $q$. Reduction with $SnCl_2/HCl$
$C$. $CH_3-CH=CH-CH_2OH$ $r$. Development of foul smell on treatment with chloroform and alcoholic $KOH$
$D$. $CH_3CH_2CH_2CH_2NH_2$ $s$. Reduction with diisobutylaluminium hydride $(DIBAL-H)$
$t$. Alkaline hydrolysis

Product $D$ is:-

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Which of the following statements is correct?

Given below are two statements:
Statement $I$: $o$-Phenylenediamine can be synthesized from $o$-xylene using simpler reagents in the order: $i)$ Acidic $KMnO_4$, $ii)$ Ammonia, $iii)$ Bromine and alkali.
Statement $II$: Aniline can be converted into benzene using reagents in the order: $(i)$ Bromine-$H_2O$, $(ii)$ $NaNO_2 / HCl$ $(0-5^{\circ} C)$, $(iii)$ aq. $H_3PO_2$.
In the light of the above statements, choose the correct answer from the options given below.

An aromatic compound $A$ on treatment with aqueous ammonia and heating forms compound $B$,which on heating with $Br_2$ and $KOH$ forms a compound $C$ of molecular formula $C_6H_7N$. Write the structures and $IUPAC$ names of compounds $A, B$,and $C$.

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