Which of the following statements is correct?

  • A
    Hinsberg reagent can be used to separate $1^o, 2^o$ and $3^o$ amines.
  • B
    Hinsberg reagent cannot be used to distinguish $1^o, 2^o$ and $3^o$ amines.
  • C
    Volatile nature of isomeric amines is $1^o > 2^o > 3^o$.
  • D
    Primary amines and secondary amines cannot be distinguished by Liebermann nitroso test.

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The following transformation can be accomplished by:

Which of the following statements is correct?

Which of the following reactions will not give a primary amine?

Complete the following reactions:
$(i)$ $C_{6}H_{5}NH_{2} + CHCl_{3} +$ alc. $KOH \rightarrow$
$(ii)$ $C_{6}H_{5}N_{2}Cl + H_{3}PO_{2} + H_{2}O \rightarrow$
$(iii)$ $C_{6}H_{5}NH_{2} + H_{2}SO_{4}$ (conc.) $\rightarrow$
$(iv)$ $C_{6}H_{5}N_{2}Cl + C_{2}H_{5}OH \rightarrow$
$(v)$ $C_{6}H_{5}NH_{2} + Br_{2(aq)} \rightarrow$
$(vi)$ $C_{6}H_{5}NH_{2} + (CH_{3}CO)_{2}O \rightarrow$
$(vii)$ $C_{6}H_{5}N_{2}Cl \xrightarrow[(ii) NaNO_{2}/Cu, \Delta ]{(i) HBF_{4}}$

Which of the following statements is not true?

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