The only $o, p-$ directing group which is deactivating in nature is

  • A
    $-NH_2$
  • B
    $-OH$
  • C
    $-X$ (halogens)
  • D
    $-R$ (alkyl groups)

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Give the product of the following reaction sequence:

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Assertion : Nitrobenzene is used as a solvent in Friedel-Craft's reaction.
Reason : Fusion of nitrobenzene with solid $KOH$ gives a low yield of a mixture of $o-$ and $p-$ nitrophenols.

Match the reactants in Column-$I$ with their products in Column-$II$.
Column-$I$ (Reactants)Column-$II$ (Products)
$(A)$ $p$-Nitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 443 \ K}$$(i)$ Phenol
$(B)$ Chlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 623 \ K, 300 \ atm}$$(ii)$ $2,4,6$-Trinitrophenol
$(C)$ $2,4$-Dinitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 368 \ K}$$(iii)$ $2,4$-Dinitrophenol
$(D)$ $2,4,6$-Trinitrochlorobenzene $\xrightarrow{Warm \ H_2O}$$(iv)$ $p$-Nitrophenol

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Identify the principal organic product of the following reaction:
$1-bromo-2-fluoro-4-nitrobenzene + NaSCH_3 \rightarrow \text{product}$

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What will be the major product in the following mononitration reaction?

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