The rate of forward reaction is two times that of reverse reaction at a given temperature and identical concentration. $K_{equilibrium}$ is

Which of the following conditions indicates a forward reaction?

$PCl_5$,$PCl_3$,and $Cl_2$ are at equilibrium at $500 \ K$ with concentrations $[PCl_3] = 1.59 \ M$,$[Cl_2] = 1.59 \ M$,and $[PCl_5] = 1.41 \ M$. Calculate $K_c$ for the reaction:
$PCl_5 \rightleftharpoons PCl_3 + Cl_2$

The decomposition of $N_2O_4$ to $NO_2$ is carried out at $280 \ K$ in chloroform. When equilibrium has been established,$0.2 \ mol$ of $N_2O_4$ and $2 \times 10^{-3} \ mol$ of $NO_2$ are present in $2 \ L$ solution. The equilibrium constant for the reaction $N_2O_4 \rightleftharpoons 2NO_2$ is:

Consider the following equilibrium reaction in gaseous state at $T(K)$.
$A(g) + 2B(g) \rightleftharpoons 2C(g) + D(g)$
The initial concentration of $B$ is $1.5$ times that of $A$. At equilibrium,the concentrations of $A$ and $B$ are equal. The equilibrium constant for the reaction is

$N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}; K_1$
$NH_{3(g)} \rightleftharpoons \frac{1}{2} N_{2(g)} + \frac{3}{2} H_{2(g)}; K_2$
$\frac{1}{2} N_{2(g)} + \frac{3}{2} H_{2(g)} \rightleftharpoons NH_{3(g)}; K_3$
$2NH_{3(g)} \rightleftharpoons N_{2(g)} + 3H_{2(g)}; K_4$
If $K_1 = K_2^x = K_3^y = K_4^z$,then the correct values of $x, y,$ and $z$ are respectively: