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(B) $(I)$ Benzene and cyclobutadiene are structural isomers (constitutional isomers) because they have different connectivity of atoms. Thus,$I-A$.$(I

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$I-A, II-A, III-B, IV-D$

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(B) $(I)$ Benzene and cyclobutadiene are structural isomers (constitutional isomers) because they have different connectivity of atoms. Thus,$I-A$.$(II)$ Cyclohexadienone and its epoxide isomer are structural isomers (constitutional isomers) because they have different functional groups and connectivity. Thus,$II-A$.$(III)$ The pair represents cis$-1,2-$dibromoethene and trans$-1,2-$dibromoethene,which are geometrical isomers,a type of configurational isomer. Thus,$III-B$.$(IV)$ The pair represents enantiomers of glyceraldehyde,which are optical isomers,a type of configurational isomer. Thus,$IV-D$.Therefore,the correct matching is $I-A, II-A, III-B, IV-D$.

The relationship among the following pairs of isomers is:

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