The relationship between standard reduction potential of a cell and the equilibrium constant is shown by:

  • A
    $E_{cell}^0 = \frac{n}{0.059} \log K_c$
  • B
    $E_{cell}^0 = \frac{0.059}{n} \log K_c$
  • C
    $E_{cell}^0 = 0.059 \, n \, \log K_c$
  • D
    $E_{cell}^0 = \frac{\log K_c}{n}$

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The standard $emf$ of a galvanic cell involving $3$ moles of electrons in its redox reaction is $0.59 \ V$. The equilibrium constant for the reaction of the cell is:

Which of the following statements is true regarding the cell emf at $298 \ K$ for the cell $Ni_{(s)} | Ni^{2+}(0.01 \ M) || Ag^{+}(0.01 \ M) | Ag_{(s)}$?

For the following electrochemical cell at $298 \ K$,
$Pt_{(s)} \mid H_2(g, 1 \ bar) \mid H^{+}(aq, 1 \ M) \parallel M^{4+}_{(aq)}, M^{2+}_{(aq)} \mid Pt_{(s)}$
$E_{\text{cell}} = 0.092 \ V$ when $\frac{[M^{2+}_{(aq)}]}{[M^{4+}_{(aq)}]} = 10^x$
Given : $E^0_{M^{4+}/M^{2+}} = 0.151 \ V$; $2.303 \frac{RT}{F} = 0.059 \ V$
The value of $x$ is

The $EMF$ of a hydrogen electrode in terms of $pH$ is (at $1 \ atm$ pressure).

For the cell at $298 \ K$:
$Ag_{(s)} | AgBr_{(s)} | Br^{-}(0.01 \ M) || I^{-}(0.02 \ M) | AgI_{(s)} | Ag_{(s)}$
The correct information is:
[Given: $K_{sp}(AgBr) = 4 \times 10^{-13}$,$K_{sp}(AgI) = 8 \times 10^{-17}$,$\frac{2.303 \ RT}{F} = 0.06 \ V$,$\log 2 = 0.3$]

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