The standard reduction potential values of the three metallic cations $x, y, z$ are $0.52 \ V, -3.03 \ V$ and $-1.18 \ V$ respectively. The order of reducing power of their corresponding metals will be

  • A
    $x > y > z$
  • B
    $z > y > x$
  • C
    $x > z > y$
  • D
    $y > z > x$

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The standard reduction electrode potentials of four metals are $A = -0.250 \ V$,$B = -0.140 \ V$,$C = -0.126 \ V$,and $D = -0.402 \ V$. Which metal can displace $A$ from its aqueous salt solution?

Electrode potential data are given below :
$Fe^{3+}_{(aq)} + e^- \to Fe^{2+}_{(aq)}; \, E^o = +0.77 \, V$
$Al^{3+}_{(aq)} + 3e^- \to Al_{(s)}; \, E^o = -1.66 \, V$
$Br_{2(aq)} + 2e^- \to 2Br^{-}_{(aq)}; \, E^o = +1.08 \, V$
Based on the data given above,the reducing power of $Fe^{2+}$,$Al$ and $Br^{-}$ will increase in the order:

Given are $E^{\circ}$ values for some half reactions:
$I_2 + 2e^{-} \to 2I^{-}$ ; $E^{\circ} = 0.54 \, V$
$MnO_4^{-} + 8H^{+} + 5e^{-} \to Mn^{2+} + 4H_2O$ ; $E^{\circ} = 1.52 \, V$
$Fe^{3+} + e^{-} \to Fe^{2+}$ ; $E^{\circ} = 0.77 \, V$
$Sn^{4+} + 2e^{-} \to Sn^{2+}$ ; $E^{\circ} = 0.1 \, V$
The strongest reducant and oxidant respectively are:

$E^o_{cell}$ for the cell: $Pt_{(s)} | H_{2(g)} | HCOOH_{(aq)} || CH_3COOH_{(aq)} | H_{2(g)} | Pt_{(s)}$ at $25^oC$ is ............ $V$. ($K_a$ of $HCOOH = 2.4 \times 10^{-4}$,$K_a$ of $CH_3COOH = 1.8 \times 10^{-5}$,$\log 2 = 0.3$,$\log 3 = 0.477$,$\frac{2.303RT}{F} = 0.059$ or $0.06$)

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The electrode potentials for $Cu^{2+}_{(aq)} + e^- \rightarrow Cu^{+}_{(aq)}$ and $Cu^{+}_{(aq)} + e^- \rightarrow Cu_{(s)}$ are $+0.15 \ V$ and $+0.50 \ V$ respectively. The value of $E^o_{Cu^{2+}/Cu}$ will be $........ \ V$.

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