(D) For a spontaneous reaction,the standard cell potential $E^{\circ}_{cell}$ must be positive.The reaction is $X + Y^{2+} \rightarrow X^{2+} + Y$.$E^

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(D) For a spontaneous reaction,the standard cell potential $E^{\circ}_{cell}$ must be positive.The reaction is $X + Y^{2+} \rightarrow X^{2+} + Y$.$E^{\circ}_{cell} = E^{\circ}_{cathode} - E^{\circ}_{anode} = E^{\circ}_{Y^{2+}/Y} - E^{\circ}_{X^{2+}/X}$.For $X = Zn$ and $Y = Ni$:$E^{\circ}_{cell} = E^{\circ}_{Ni^{2+}/Ni} - E^{\circ}_{Zn^{2+}/Zn} = -0.23 \ V - (-0.76 \ V) = +0.53 \ V$.Since $E^{\circ}_{cell} > 0$,the reaction is spontaneous.

Class 12 Chemistry Electrochemistry Electrode potential and ECell

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The standard reduction potentials for $Zn^{2+}/Zn$,$Ni^{2+}/Ni$ and $Fe^{2+}/Fe$ are $-0.76 \ V$,$-0.23 \ V$ and $-0.44 \ V$ respectively.
The reaction $X + Y^{2+} \rightarrow X^{2+} + Y$ will be spontaneous when:

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A
$X = Ni, Y = Fe$
B
$X = Ni, Y = Zn$
C
$X = Fe, Y = Zn$
D
$X = Zn, Y = Ni$

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Electrode potential and ECell

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In which metal container can an aqueous solution of $CuSO_4$ be stored?
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Calculate the standard free energy change for the reaction $\frac{1}{2}Cu_{(s)} + \frac{1}{2}Cl_{2(g)} \rightleftharpoons \frac{1}{2}Cu^{2+} + Cl^-$ taking place at $25\ ^oC$ in a cell whose standard e.m.f. is $1.02 \ V$ (in $J$).

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Standard electrode potential of three metals $X$,$Y$ and $Z$ are $-1.2 \, V$,$+0.5 \, V$ and $-3.0 \, V$ respectively. The reducing power of these metals will be

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If the standard reduction potentials for four divalent elements $X, Y, Z,$ and $W$ are $-1.46 \ V, -0.36 \ V, 0.15 \ V,$ and $-1.24 \ V$ respectively,then:

Medium

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The reduction potential ($E^{\circ}$,in $V$) of $MnO_4^-{_{\text{(aq)}}} / Mn_{\text{(s)}}$ is. . . . . $[Given : E^{\circ}_{(MnO_4^{-(aq)} / MnO_{2(s)})} = 1.68 \ V ; E^{\circ}_{(MnO_{2(s)} / Mn^{2+}_{(aq)})} = 1.21 \ V ; E^{\circ}_{(Mn^{2+(aq)} / Mn_{(s)})} = -1.03 \ V]$

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The standard reduction potentials for $Zn^{2+}/Zn$,$Ni^{2+}/Ni$ and $Fe^{2+}/Fe$ are $-0.76 \ V$,$-0.23 \ V$ and $-0.44 \ V$ respectively.The reaction $X + Y^{2+} \rightarrow X^{2+} + Y$ will be spontaneous when:

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In which metal container can an aqueous solution of $CuSO_4$ be stored? $E^0_{Cu^{2+}/Cu} = 0.34 \ V$,$E^0_{Fe/Fe^{2+}} = 0.44 \ V$,$E^0_{Al/Al^{3+}} = 1.66 \ V$,$E^0_{Ni/Ni^{2+}} = 0.25 \ V$,$E^0_{Ag^{+}/Ag} = 0.80 \ V$

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Standard electrode potential of three metals $X$,$Y$ and $Z$ are $-1.2 \, V$,$+0.5 \, V$ and $-3.0 \, V$ respectively. The reducing power of these metals will be

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The standard reduction potentials for $Zn^{2+}/Zn$,$Ni^{2+}/Ni$ and $Fe^{2+}/Fe$ are $-0.76 \ V$,$-0.23 \ V$ and $-0.44 \ V$ respectively.
The reaction $X + Y^{2+} \rightarrow X^{2+} + Y$ will be spontaneous when:

In which metal container can an aqueous solution of $CuSO_4$ be stored?
$E^0_{Cu^{2+}/Cu} = 0.34 \ V$,$E^0_{Fe/Fe^{2+}} = 0.44 \ V$,$E^0_{Al/Al^{3+}} = 1.66 \ V$,$E^0_{Ni/Ni^{2+}} = 0.25 \ V$,$E^0_{Ag^{+}/Ag} = 0.80 \ V$