This reaction is an example of:

Convert:
$(i)$ $3-$Methylaniline into $3-$nitrotoluene.
$(ii)$ Aniline into $1,3,5-$tribromobenzene.

Match List-$I$ with List-$II$ and select the correct answer.

List-$I$	List-$II$
$1.$ Aniline	$a.$ Used in the preparation of azo dyes
$2.$ Nitrobenzene	$b.$ Sulpha drug
$3.$ Sulphanilamide	$c.$ Solvent in Friedel-Crafts reaction
$4.$ Trinitrotoluene	$d.$ Used as an explosive

What is the product obtained when the product of alkaline hydrolysis of $C_2H_5 - N = C = O$ is reacted with $t$-butyl magnesium bromide?

$A$ hydrocarbon $'A'$ $(C_4H_8)$ on reaction with $HCl$ gives a compound $'B'$ $(C_4H_9Cl)$,which on reaction with $1 \ mol$ of $NH_3$ gives compound $'C'$ $(C_4H_{11}N)$. On reacting with $NaNO_2$ and $HCl$ followed by treatment with water,compound $'C'$ yields an optically active alcohol,$'D'$. Ozonolysis of $'A'$ gives $2 \ mols$ of acetaldehyde. Identify compounds $'A'$ to $'D'$. Explain the reactions involved.

Product $D$ is:-