What is the effect of increasing temperature on surface tension?

On heating water,bubbles formed at the bottom of the vessel detach and rise. Assume the bubbles are spheres of radius $R$ and make a circular contact of radius $r$ with the bottom of the vessel. If $r << R$ and the surface tension of water is $T$,find the value of $r$ just before the bubbles detach. (Density of water is $\rho_{w}$)

When liquid medicine of density $\rho$ is to be put in the eye, it is done with the help of a dropper. As the bulb on the top of the dropper is pressed, a drop forms at the opening of the dropper. We wish to estimate the size of the drop. We first assume that the drop formed at the opening is spherical because that requires a minimum increase in its surface energy. To determine the size, we calculate the net vertical force due to the surface tension $T$ when the radius of the drop is $R$. When the force becomes smaller than the weight of the drop, the drop gets detached from the dropper.
$1.$ If the radius of the opening of the dropper is $r$, the vertical force due to the surface tension on the drop of radius $R$ (assuming $r \ll R$) is
$(A)$ $2 \pi r T$ $(B)$ $2 \pi R T$ $(C)$ $\frac{2 \pi r^2 T}{R}$ $(D)$ $\frac{2 \pi R^2 T}{r}$
$2.$ If $r=5 \times 10^{-4} \, m, \rho=10^3 \, kg \, m^{-3}, g=10 \, m/s^2, T=0.11 \, Nm^{-1}$, the radius of the drop when it detaches from the dropper is approximately
$(A)$ $1.4 \times 10^{-3} \, m$ $(B)$ $3.3 \times 10^{-3} \, m$
$(C)$ $2.0 \times 10^{-3} \, m$ $(D)$ $4.1 \times 10^{-3} \, m$
$3.$ After the drop detaches, its surface energy is
$(A)$ $1.4 \times 10^{-6} \, J$ $(B)$ $2.7 \times 10^{-6} \, J$
$(C)$ $5.4 \times 10^{-6} \, J$ $(D)$ $8.1 \times 10^{-6} \, J$
Give the answer for questions $1, 2$ and $3.$

The property utilized in the manufacture of lead shots is

$A$ thin flat circular disc of radius $4.5 \,cm$ is placed gently over the surface of water. If the surface tension of water is $0.07 \,N \,m^{-1}$, then the excess force required to take it away from the surface is

$A$ metal wire of density $\rho$ floats on the water surface horizontally. If it is not to sink in water,then the maximum radius of the wire is ($T$ = surface tension of water,$g$ = gravitational acceleration).