Which among the following has the highest melting point?

If $x > 0, y > 0, z > 0, xy + yz + zx < 1$ and if $\tan^{-1} x + \tan^{-1} y + \tan^{-1} z = \pi$,then $x + y + z$ equals to

$A$ ball is falling freely from a height. When it reaches $10 ~m$ height from the ground,its velocity is $v_0$. It collides with the ground,loses $50 \%$ of its energy,and rises back to a height of $10 ~m$. Then the velocity $v_0$ is (in $~m/s$)

$Na^+$,$Mg^{2+}$,$Al^{3+}$,and $Si^{4+}$ are isoelectronic. What is the order of their ionic radii?

If $\bar{a}$ and $\bar{b}$ are two unit vectors such that $\bar{a}+2 \bar{b}$ and $5 \bar{a}-4 \bar{b}$ are perpendicular to each other,then the angle between $\bar{a}$ and $\bar{b}$ is