Compare the rates $(R_1, R_2, R_3)$ of the following solvolysis reactions in ethanol $(EtOH)$:

  • A
    $R_1 > R_2 > R_3$
  • B
    $R_3 > R_2 > R_1$
  • C
    $R_2 > R_1 > R_3$
  • D
    $R_2 > R_3 > R_1$

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Match the reactions in column $I$ with appropriate types of steps/reactive intermediate involved in these reactions as given in column $II$.
| Column $I$ | Column $II$ |
| :--- | :--- |
| $(A)$ $1-$phenylpentane$-1,4-$dione $\xrightarrow{aq. NaOH}$ $3-$phenylcyclopent$-2-$en$-1-$one | $(p)$ Nucleophilic substitution |
| $(B)$ $4-$chloro$-1-$phenylbutan$-1-$one $\xrightarrow{CH_3MgI}$ $2-$methyl$-2-$phenyltetrahydrofuran | $(q)$ Electrophilic substitution |
| $(C)$ $4-$hydroxy$-1-$phenylbutan$-1-$one $\xrightarrow{H_2SO_4}$ $2-$phenyl$-4,5-$dihydrofuran | $(r)$ Dehydration |
| $(D)$ $4-$methyl$-4-$phenylpentan$-1-$ol $\xrightarrow{H_2SO_4}$ $1,1-$dimethyl$-1,2,3,4-$tetrahydronaphthalene | $(s)$ Nucleophilic addition |
| | $(t)$ Carbanion |

For the given molecule, $x$, the preferred site for the attack of the electrophile is:

Based on the provided energy profile diagram,transition state $2$ $(T.S. 2)$ is structurally most likely similar to which of the following?

The enol percentage of the following compound is maximum for:

Difficult
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Consider the above reaction,the major product $P$ formed is:

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