Which of the following alkyl halides undergoes rearrangement in an $S_{N}1$ reaction?

  • A
    $CH_3-C(CH_3)_2-CH(I)-CH_3$
  • B
    $1-$chloro$-2-$methylcyclohexane
  • C
    $3-$iodocyclohexene
  • D
    All of these

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Given below are two statements:
Statement $I$: $C-Cl$ bond is stronger in $CH_2=CH-Cl$ than $CH_3-CH_2-Cl$.
Statement $II$: The given optically active molecule on hydrolysis gives a solution that can rotate the plane polarized light.
In the light of the above statements, choose the correct answer from the options given below.

$C_3H_7I$ $(P)$ $\xrightarrow[\text{alc. } KOH]{\Delta}$ $Q$ $\xrightarrow{NBS}$ $R$ $\xrightarrow{KCN}$ $CH_2 = CH - CH_2 - CN$. $P$ can be:

Given below are two statements:
Statement $I$: Due to increase in van der Waals forces, the order of boiling points is $CH_3CH_2CH_2I > CH_3CH_2I > CH_3I$.
Statement $II$: As $para$-dichlorobenzene is more symmetric, its melting point is higher than $ortho$-dichlorobenzene, however its boiling point is lower than $ortho$-dichlorobenzene.
In the light of the above statements, choose the correct answer from the options given below:

The major product for the following reaction is:

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Match the reactions in Column-$A$ with the products in Column-$B$ and select the correct option:
Column-$A$Column-$B$
$(1)$ $CH_3-CH_2-Cl + KOH_{(aq)} \rightarrow$$(A)$ $1,2-\text{dichloroethane}$
$(2)$ $CH_3-CH_2-CH_2-CH_3 \xrightarrow{AlCl_3/HCl}$$(B)$ $\text{Chloromethane}$
$(3)$ $CH_3-CH_2-Br + \text{alc. } KOH \rightarrow$$(C)$ $\text{But-2-ene}$
$(4)$ $CH_2=CH_2 + Cl_2 \rightarrow$$(D)$ $\text{Ethanol}$
$(E)$ $\text{Chloroethane}$
$(F)$ $\text{Ethene}$
$(G)$ $\text{Isobutane}$

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