Which of the following are used as catalysts in petroleum cracking?

Pick out the incorrect statement:

$Cr_2O_7^{2-} \underset{Y}{\overset{X}{\longleftrightarrow}} 2CrO_4^{2-}$,$X$ and $Y$ are respectively

$Fe_2Cr_2O_4 + Na_2CO_3 + O_2$ $\xrightarrow{\text{Fusion}} [X]$ $\xrightarrow[H_2O]{H^{+}} [Y]$ $\xrightarrow{H_2O_2/H^{+}} [Z]$
Which of the following statements is true for the compounds $[X]$,$[Y]$,and $[Z]$?

When $XO_2$ is fused with an alkali metal hydroxide in the presence of an oxidizing agent such as $KNO_3$,a dark green product is formed which disproportionates in an acidic solution to afford a dark purple solution. $X$ is

$Orange-(A)$ (Inorganic compound) $+ H^{+} + H_2O_2 \to Blue-(B)$. The oxidation state of the central atom in compound $(B)$ is: