Which of the following pairs represent linkag | vedclass

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(A) Linkage isomerism occurs in coordination compounds containing ambidentate ligands,which can bind to the central metal atom through two different d

Vedclass · Accepted Answer

$[Pd(PH_3)_2(NCS)_2]$ and $[Pd(PH_3)_2(SCN)_2]$

Vedclass · Answer

(A) Linkage isomerism occurs in coordination compounds containing ambidentate ligands,which can bind to the central metal atom through two different donor atoms.In the pair $[Pd(PH_3)_2(NCS)_2]$ and $[Pd(PH_3)_2(SCN)_2]$,the ligand $SCN^-$ is an ambidentate ligand.It can coordinate through the sulfur atom $(S)$ to form thiocyanato complexes $(M-SCN)$ or through the nitrogen atom $(N)$ to form isothiocyanato complexes $(M-NCS)$.Therefore,this pair represents linkage isomers.

Which of the following pairs represent linkage isomers?

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