Which of the following statements is incorrect?

  • A
    $NO_3^{\ominus}$ ion oxidises $Cu$ but $H^{\oplus}$ ion cannot oxidise $Cu$.
  • B
    $AgNO_3$ solution cannot be stored in a copper container.
  • C
    Hydrogen gas can reduce Zinc ion $(Zn^{2+})$.
  • D
    $F^{\ominus}$ ion is the weakest reducing agent.

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For a saturated solution of $Ag_{2}CrO_{4}$ at infinite dilution,$\lambda_{m}^{\infty}(Ag^{+}) = 127 \ \Omega^{-1} \ cm^{2} \ mol^{-1}$ and $\lambda_{m}^{\infty}(CrO_{4}^{2-}) = 246 \ \Omega^{-1} \ cm^{2} \ mol^{-1}$. If the specific conductance of the solution is $2 \times 10^{-2} \ \Omega^{-1} \ cm^{-1}$,calculate the solubility product $(K_{sp})$ of $Ag_{2}CrO_{4}$.

Consider the following statements pertaining to fuel cells :-
$(a)$ Hydrogen-oxygen fuel cells make use of concentrated $KOH$ solution as an electrolyte and porous graphite impregnated with platinum as electrodes.
$(b)$ The efficiency of a fuel cell is less than unity due to polarization at electrodes and the resistance offered by the electrode and the electrolyte.
$(c)$ The electrical work,assuming the cell to be working reversibly,may be represented as $-\Delta G = W_{\text{electrical}} = -\Delta H + T\Delta S$.
Which of the above statements are correct?

Consider the following cell reaction:
$Cd_{(s)} + Hg_{2}SO_{4(s)} + \frac{9}{5}H_{2}O_{(l)} \rightleftharpoons CdSO_{4} \cdot \frac{9}{5}H_{2}O_{(s)} + 2Hg_{(l)}$
The value of $E_{\text{cell}}^{0}$ is $4.315 \ V$ at $25^{\circ}C$. If $\Delta H^{\circ} = -825.2 \ kJ \ mol^{-1}$,the standard entropy change $\Delta S^{\circ}$ in $J \ K^{-1} \ mol^{-1}$ is ........ . (Nearest integer) [Given: Faraday constant $= 96487 \ C \ mol^{-1}$]

All the energy released from the reaction $X \rightarrow Y, \Delta_{r}G^0 = -193 \ kJ \ mol^{-1}$ is used for oxidizing $M^{+}$ as $M^{+} \rightarrow M^{3+} + 2e^-, E^0 = -0.25 \ V$. Under standard conditions,the number of moles of $M^{+}$ oxidized when one mole of $X$ is converted to $Y$ is $\left[F = 96500 \ C \ mol^{-1}\right]$.

Identify the correct statements from the following:
$(A)$ At $298 \ K$,the potential of a hydrogen electrode placed in a solution of $pH = 10$ is $-0.59 \ V$.
$(B)$ The limiting molar conductivity of $Ca^{2+}$ and $Cl^{-}$ are $119$ and $76 \ S \ cm^2 \ mol^{-1}$ respectively. The limiting molar conductivity of $CaCl_2$ is $195 \ S \ cm^2 \ mol^{-1}$.
$(C)$ The correct relationship between $K_{c}$ and $E_{cell}^{0}$ is $E_{cell}^{0} = \frac{2.303 RT}{nF} \log K_{c}$.

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