Which of the following statements is correct regarding the $emf$ of the cell for the cell reaction,$Cd_{(s)} + Cu^{2+}_{(aq)} \longrightarrow Cd^{2+}_{(aq)} + Cu_{(s)}$,if the concentration of $Cd^{2+}$ is $10$ times greater than the concentration of $Cu^{2+}_{(aq)}$ at $298 \ K$?

  • A
    greater than $E^{\circ}_{cell}$ by $0.0592 \ V$
  • B
    less than $E^{\circ}_{cell}$ by $0.0592 \ V$
  • C
    greater than $E^{\circ}_{cell}$ by $0.0296 \ V$
  • D
    less than $E^{\circ}_{cell}$ by $0.0296 \ V$

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Similar Questions

In which of the following Galvanic cells is the $emf$ maximum? (Given: $E_{Mg^{2+} \mid Mg}^0 = -2.36 \ V$ and $E_{Cl_2 \mid 2 Cl^{-}}^0 = +1.36 \ V$)

The $emf$ of a $Daniel$ cell at $298 \ K$ is ${E_1}$ for the cell reaction $Zn|ZnSO_4(0.01 \ M)||CuSO_4(1.0 \ M)|Cu$. When the concentration of $ZnSO_4$ is $1.0 \ M$ and that of $CuSO_4$ is $0.01 \ M$,the $emf$ changes to ${E_2}$. What is the relationship between ${E_1}$ and ${E_2}$?

Identify the correct statement$(s)$:

The reduction potential of a hydrogen half-cell will be negative if:

The photoelectric current from $Na$ (work function,$w_{0}=2.3 \ eV$) is stopped by the output voltage of the cell
$Pt_{(s)} | H_{2}(g, 1 \ bar) | HCl(aq, pH=1) | AgCl_{(s)} | Ag_{(s)}$
The $pH$ of aqueous $HCl$ required to stop the photoelectric current from $K$ $(w_{0}=2.25 \ eV)$,all other conditions remaining the same,is..........$\times 10^{-2}$ (to the nearest integer).
Given,$2.303 \frac{RT}{F}=0.06 \ V; E_{AgCl|Ag|Cl^{-}}^{0}=0.22 \ V$

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