Which of the following volume $(V)$-temperature $(T)$ plots represents the behaviour of one mole of an ideal gas at one atmospheric pressure?

$1 \text{ mole}$ of gas $A$ and $1 \text{ mole}$ of gas $B$ at $27^{\circ} C$ were pumped into a $24.6 \ L$ volume pre-evacuated isolated flask. The catalyst coated inside the flask catalyses the following reaction $A_{(g)} + B_{(g)} \longrightarrow 2 D_{(g)}$. The kinetic energy of $D$ is $98.03 \ L \ atm$. Calculate the pressure realized at the end of the reaction. (in $atm$)

What is the temperature at which the kinetic energy of $0.3 \text{ moles}$ of helium is equal to the kinetic energy of $0.4 \text{ moles}$ of argon at $400 \text{ K}$ (in $\text{ K}$)?

At $STP$,what is the actual volume occupied by the molecules of $1 \, \text{mol}$ of water vapor (i.e.,$\text{Avogadro's number} \times \text{volume of one molecule}$)?

At $STP$,a closed vessel contains $1 \ mole$ each of $He$ and $CH_4$. Through a small hole,$2 \ L$ of $He$ and $1 \ L$ of $CH_4$ escaped from the vessel in '$t$' minutes. What are the mole fractions of $He$ and $CH_4$ respectively remaining in the vessel? (Assume $He$ and $CH_4$ as ideal gases. At $STP$,one mole of an ideal gas occupies $22.4 \ L$ of volume.)

During winter,when taking a bath,water vapour appears. Explain the physical process.