Which one of the following statements is correct when $SO_2$ is passed through acidified $K_2Cr_2O_7$ solution?

In the reaction $4K_2Cr_2O_7 \xrightarrow{\text{heat}} 4K_2CrO_4 + 3O_2 + X$,identify $X$.

$Orange-(A)$ (Inorganic compound) $+ H^{+} + H_2O_2 \to Blue-(B)$. The oxidation state of the central atom in compound $(B)$ is:

The colorless species is

Which one of the following ions participates in the production of $ATP$ from the oxidation of glucose?

Fusion of $MnO_2$ with $KOH$ in presence of $O_2$ produces a salt $W$. Alkaline solution of $W$ upon electrolytic oxidation yields another salt $X$. The manganese containing ions present in $W$ and $X$,respectively,are $Y$ and $Z$. Correct statement$(s)$ is (are)
$(1)$ $Y$ is diamagnetic in nature while $Z$ is paramagnetic
$(2)$ Both $Y$ and $Z$ are coloured and have tetrahedral shape
$(3)$ In both $Y$ and $Z$,$\pi$-bonding occurs between $p$-orbitals of oxygen and $d$-orbitals of manganese.
$(4)$ In aqueous acidic solution,$Y$ undergoes disproportionation reaction to give $Z$ and $MnO_2$.