Which statement about the composition of vapour over an ideal $1:1$ molar mixture of benzene and toluene is correct? Assume the temperature is constant at $25\,^{\circ}C$. Vapour pressure data $(25\,^{\circ}C)$:
Benzene: $75\, mm\, Hg$
Toluene: $22\, mm\, Hg$

  • A
    The vapour will contain higher percentage of benzene
  • B
    The vapour will contain higher percentage of toluene
  • C
    The vapour will contain equal amount of benzene and toluene
  • D
    Not enough information is given to make a prediction

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Which of the following mixture$(s)$ show$(s)$ positive deviation from Raoult's law at $35^{\circ}C$?
$(A)$ Carbon tetrachloride + methanol
$(B)$ Carbon disulphide + acetone
$(C)$ Benzene + toluene
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When acetone is added to chloroform,then a hydrogen bond is formed between them. These liquids show:

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$(A)$ $\Delta G_{mix} < 0$
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$(C)$ $\Delta V_{mix} = 0$
$(D)$ $\Delta_{mix} H = 0$

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