Which will give $Fe^{3+}$ ions in solution?

  • A
    $[Fe(CN)_6]^{3-}$
  • B
    $Fe_2(SO_4)_3$
  • C
    $[Fe(CN)_6]^{4-}$
  • D
    $(NH_4)_2SO_4 \cdot FeSO_4 \cdot 6H_2O$

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Match List-$I$ with List-$II$ and select the correct option:
List-$I$List-$II$
$(A). [Ag(CN)_2]^-$$1. \text{Square planar, } 1.73 \, B.M.$
$(B). [Cu(CN)_4]^{3-}$$2. \text{Linear, } 0 \, B.M.$
$(C). [Cu(CN)_6]^{4-}$$3. \text{Octahedral, } 0 \, B.M.$
$(D). [Cu(NH_3)_4]^{2+}$$4. \text{Tetrahedral, } 0 \, B.M.$
$(E). [Fe(CN)_6]^{4-}$$5. \text{Octahedral, } 1.73 \, B.M.$

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The reaction of $K_3[Fe(CN)_6]$ with freshly prepared $FeSO_4$ solution produces a dark blue precipitate called Turnbull's blue. The reaction of $K_4[Fe(CN)_6]$ with $FeSO_4$ solution in the complete absence of air produces a white precipitate $X$,which turns blue in air. Mixing the $FeSO_4$ solution with $NaNO_3$,followed by a slow addition of concentrated $H_2SO_4$ through the side of the test tube,produces a brown ring.
Precipitate $X$ is:
$(A)$ $Fe_4[Fe(CN)_6]_3$
$(B)$ $Fe[Fe(CN)_6]$
$(C)$ $K_2Fe[Fe(CN)_6]$
$(D)$ $KFe[Fe(CN)_6]$
Among the following,the brown ring is due to the formation of:
$(A)$ $[Fe(NO)_2(SO_4)_2]^{2-}$
$(B)$ $[Fe(NO)_2(H_2O)_4]^{3+}$
$(C)$ $[Fe(NO)_4(SO_4)_2]$
$(D)$ $[Fe(H_2O)_5(NO)]SO_4$

Given below are two statements:
Statement $I$: $PF_5$ and $BrF_5$ both exhibit $sp^3 d$ hybridisation.
Statement $II$: Both $SF_6$ and $[Co(NH_3)_6]^{3+}$ exhibit $sp^3 d^2$ hybridisation.
In the light of the above statements,choose the correct answer from the options given below:

Write down the $IUPAC$ name for each of the following complexes and indicate the oxidation state,electronic configuration,and coordination number. Also,give the stereochemistry and magnetic moment of the complex:
$(i)$ $K[Cr(H_2O)_2(C_2O_4)_2] \cdot 3H_2O$
$(ii)$ $[Co(NH_3)_5Cl]Cl_2$
$(iii)$ $CrCl_3(py)_3$
$(iv)$ $Cs[FeCl_4]$
$(v)$ $K_4[Mn(CN)_6]$

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Given below are two statements:
Statement $I$ : Dimethyl glyoxime forms a six-membered covalent chelate when treated with $NiCl_2$ solution in presence of $NH_4OH$.
Statement $II$ : Prussian blue precipitate contains iron both in $(+2)$ and $(+3)$ oxidation states.
In the light of the above statements,choose the most appropriate answer from the options given below:

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