Write a note on Kolbe's reaction.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Kolbe's reaction is a chemical reaction used to synthesize salicylic acid from phenol.
$1$. Phenol is treated with sodium hydroxide $(NaOH)$ to form sodium phenoxide.
$2$. Sodium phenoxide is then reacted with carbon dioxide $(CO_2)$ at a temperature of $398 \ K$ and a pressure of $4-7 \ bar$.
$3$. This leads to the formation of sodium salicylate,which upon acidification with concentrated hydrochloric acid $(HCl)$ yields salicylic acid ($2$-hydroxybenzoic acid).
Reaction sequence:
$C_6H_5OH + NaOH \rightarrow C_6H_5ONa + H_2O$
$C_6H_5ONa + CO_2 \xrightarrow{398 \ K, 4-7 \ bar} C_6H_4(OH)COONa$
$C_6H_4(OH)COONa + H^+ \rightarrow C_6H_4(OH)COOH$ (Salicylic acid)

Explore More

Similar Questions

The most suitable method for the separation of a $1:1$ mixture of $o-$ and $p-$ nitrophenols is:

Which oxidizing agent is used to obtain chloranil from the oxidation of phenol?

Difficult
View Solution

Phenol is:

Phenol $\xrightarrow{Br_2 / H_2O}$ Product formed is

Out of the two compounds shown below,the vapour pressure of $B$ at a particular temperature is expected to be:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo