Write a note on the standard hydrogen electrode $(SHE)$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) According to the convention,a half-cell called the standard hydrogen electrode $(SHE)$,represented by $Pt_{(s)} | H_{2_{(g)}} (1 \ bar) | H^{+}_{(aq)} (1 \ M)$,is assigned a zero potential at all temperatures.
Construction of hydrogen electrode:
The standard hydrogen electrode consists of a platinum electrode coated with platinum black. The electrode is dipped in an acidic solution,and pure hydrogen gas is bubbled through it at $1 \ bar$ pressure.
The concentration of hydrogen ions in the solution is maintained at $1 \ M$.
The half-cell reactions are:
Oxidation: $\frac{1}{2} H_{2_{(g)}} \longrightarrow H^{+}_{(aq)} + e^{-}$
Reduction: $H^{+}_{(aq)} + e^{-} \longrightarrow \frac{1}{2} H_{2_{(g)}}$
Uses:
The standard hydrogen electrode is used as a reference electrode to measure the electrode potential of any other half-cell. By constructing a galvanic cell with the $SHE$ and another electrode,the measured cell potential at $298 \ K$ directly gives the potential of that half-cell,as the potential of the $SHE$ is taken as zero.

Explore More

Similar Questions

The standard electrode potentials of $Ag^{+}/Ag$,$Hg_2^{2+}/2Hg$,$Cu^{2+}/Cu$,and $Mg^{2+}/Mg$ are $0.80 \ V$,$0.79 \ V$,$0.34 \ V$,and $-2.37 \ V$,respectively. An aqueous solution containing $1 \ M$ concentration of each of these metal salts is electrolyzed. With increasing voltage,what is the correct sequence of deposition of the metals at the cathode?

The standard electrode potentials $E^{\circ} (V)$ for $Li^{+} / Li$ and $Na^{+} / Na$ respectively are:

Given $E^{0}_{Fe^{2+}|Fe} = -0.441 \, V$ and $E^{0}_{Fe^{3+}|Fe^{2+}} = 0.771 \, V$,calculate the standard $EMF$ for the reaction $Fe + 2Fe^{3+} \rightarrow 3Fe^{2+}$ in $V$.

Difficult
View Solution

The standard oxidation potential of a calomel electrode is:

The standard reduction potential for $Mg^{2+}/Mg$ is $-2.37 \ V$ and for $Cu^{2+}/Cu$ is $0.337 \ V$. The $E^{\circ}_{cell}$ for the following reaction is $Mg + Cu^{2+} \longrightarrow Mg^{2+} + Cu$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo