In which of the following reactions is a tertiary amine formed?

The compounds $X$ and $Y$ are respectively:

An amine $(X)$ is prepared by ammonolysis of benzyl chloride. On adding $p-$toluenesulphonyl chloride to it,the solution remains clear. The molar mass of the amine $(X)$ formed is $g \ mol^{-1}$. (Given molar mass in $g \ mol^{-1}$: $C=12, H=1, O=16, N=14, S=32, Cl=35.5$)

$CH_3CH_2CONH_2$ $\xrightarrow{Br_2 / KOH_{(aq)}} X$ $\xrightarrow{C_6H_5COCl} Y$. Which statement is true?

Complete the following reactions:
$(i)$ $C_{6}H_{5}NH_{2} + CHCl_{3} +$ alc. $KOH \rightarrow$
$(ii)$ $C_{6}H_{5}N_{2}Cl + H_{3}PO_{2} + H_{2}O \rightarrow$
$(iii)$ $C_{6}H_{5}NH_{2} + H_{2}SO_{4}$ (conc.) $\rightarrow$
$(iv)$ $C_{6}H_{5}N_{2}Cl + C_{2}H_{5}OH \rightarrow$
$(v)$ $C_{6}H_{5}NH_{2} + Br_{2(aq)} \rightarrow$
$(vi)$ $C_{6}H_{5}NH_{2} + (CH_{3}CO)_{2}O \rightarrow$
$(vii)$ $C_{6}H_{5}N_{2}Cl \xrightarrow[(ii) NaNO_{2}/Cu, \Delta ]{(i) HBF_{4}}$

Match the reactions given in Column-$I$ with the statements given in Column-$II$.

Column-$I$	Column-$II$
$A$. Ammonolysis	$1$. Amine with lesser number of carbon atoms
$B$. Gabriel phthalimide synthesis	$2$. Detection test for primary amine
$C$. Hoffmann Bromamide reaction	$3$. Reaction of phthalimide with $KOH$ and $R-X$
$D$. Carbylamine reaction	$4$. Reaction of alkyl-halides with $NH_3$