$A$ chemical reaction cannot occur at all if

  • A
    $ \Delta H $ value is positive and $ \Delta S $ value is negative
  • B
    $ \Delta H $ value is negative and $ \Delta S $ value is positive
  • C
    $ \Delta H $ and $ \Delta S $ values are negative but $ \Delta H > T \Delta S $
  • D
    $ \Delta H $ and $ \Delta S $ values are positive but $ \Delta H > T \Delta S $

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What happens during a spontaneous process?

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For a given chemical reaction $A \rightarrow B$ at $300 \ K$,the free energy change is $-49.4 \ kJ \ mol^{-1}$ and the enthalpy of reaction is $51.4 \ kJ \ mol^{-1}$. The entropy change of the reaction is $..... \ J \ K^{-1} \ mol^{-1}$.

For a given reaction,$\Delta H = 35.5 \ kJ \ mol^{-1}$ and $\Delta S = 83.6 \ J \ K^{-1} \ mol^{-1}$. The reaction is spontaneous at (Assume that $\Delta H$ and $\Delta S$ do not vary with temperature.)

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