At $300 \ K$,which of the following reactions with the given thermodynamic parameters occur spontaneously?

$1 \ g$ of graphite is burnt in a bomb calorimeter in excess of oxygen at $298 \ K$ and $1 \ atm$ atmospheric pressure according to the equation:
$C \ (graphite) + O_{2(g)} \rightarrow CO_{2(g)}$
During the reaction,the temperature rises from $298 \ K$ to $299 \ K$. If the heat capacity of the bomb calorimeter is $20.7 \ kJ \ K^{-1}$,what is the enthalpy change for the above reaction at $298 \ K$ and $1 \ atm$?

Which one of the following is always not negative?

The heat change for the following reaction at $298 \ K$ and at constant pressure is $+ 7.3 \ kcal$. $A_2B_{(s)} \to 2A_{(s)} + 1/2 \ B_{2(g)}$,$\Delta H = + 7.3 \ kcal$. The heat change at constant volume would be

The following reaction occurs in an automobile: $2C_8H_{18(g)} + 25O_{2(g)} \to 16CO_{2(g)} + 18H_2O_{(g)}$. The signs of $\Delta H$,$\Delta S$,and $\Delta G$ would be:

The amount of heat released when $20 \ mL$ of $0.5 \ M$ $NaOH$ is mixed with $100 \ mL$ of $0.1 \ M$ $HCl$ is $x \ kJ$. The heat of neutralization is: