Explain the structures of diborane and boric acid.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) $B_2H_6$ is an electron-deficient compound. It has only $12$ valence electrons: $6$ from $6$ $H$ atoms and $3$ each from $2$ $B$ atoms. Thus,after forming $3$ terminal $B-H$ bonds,the boron atoms have no electrons left for bridging. $X$-ray diffraction studies reveal the structure of diborane:
$1$. Two boron and four terminal hydrogen atoms $(H_t)$ lie in one plane.
$2$. The two bridging hydrogen atoms $(H_b)$ lie in a plane perpendicular to the plane of the boron atoms,one above and one below.
$3$. The terminal bonds are regular two-centre two-electron $(2c-2e^-)$ bonds.
$4$. The two bridging $(B-H-B)$ bonds are three-centre two-electron $(3c-2e^-)$ bonds,often called banana bonds.
Boric acid $(H_3BO_3)$:
Boric acid has a layered structure. Each planar $BO_3^{3-}$ unit is linked to others through hydrogen bonds. The $H$ atoms form a covalent bond with oxygen in one $BO_3$ unit,while forming a hydrogen bond with oxygen in another $BO_3$ unit. The dotted lines in the structure represent these hydrogen bonds.

Explore More

Similar Questions

Two polaroids are placed in the path of an unpolarized beam of intensity $I_0$ such that no light is emitted from the second polaroid. If a third polaroid,whose polarization axis makes an angle $\theta$ with the polarization axis of the first polaroid,is placed between these polaroids,then the intensity of light emerging from the last polaroid will be

The correct order of acidic strength of the major products formed in the given reactions is:
$A.$ $PhNH_2$ $\xrightarrow[\substack{\text{(2) } CuCN \\ \text{(3) } H_3O^{+} / \Delta}]{\text{(1) } NaNO_2 + HCl \left( < 5^{\circ} C \right)} [A]$
$B.$ $CH_3CH_2CHO \xrightarrow[\Delta]{\left[ Ag \left( NH_3\right)_2\right]^{+}, OH^{-}} [B]$
$C.$ $CH_4 + O_2 \xrightarrow[\text{(ii) } Na_2Cr_2O_7 / H^{+}]{\text{(i) } Mo_2O_3} [C]$
$D.$ $PhCH_2MgBr + CO_2 \xrightarrow[H_3O^{+}]{\text{Dry ether}} [D]$
Choose the correct answer from the options given below:

Breeding of crops with high levels of minerals,vitamins,and proteins is called:

The major product of the following reaction is

When metal $X$ is treated with sodium hydroxide,a white precipitate $(A)$ is obtained,which is soluble in excess of $NaOH$ to give soluble complex $(B)$. Compound $(A)$ is soluble in dilute $HCl$ to form compound $(C)$. The compound $(A)$ when heated strongly gives $(D)$,which is used to extract metal. Identify $(X), (A), (B), (C)$ and $(D)$. Write suitable equations to support their identities.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo