Identify the false statement:

Assertion : If one component of a solution obeys Raoult's law over a certain range of composition,the other component will not obey Henry's law in that range.
Reason : Raoult's law is a special case of Henry's law.

An aqueous solution of urea (molar mass $= 60 \ g \ mol^{-1}$) boils at $100.18^o C$ at atmospheric pressure. If $K_f = 1.86 \ K \ kg \ mol^{-1}$ and $K_b = 0.512 \ K \ kg \ mol^{-1}$ for water,then the freezing point of the solution is equal to ..... $^o C$.

In the depression of freezing point experiment,it is found that the:

When a solute is added to a solvent,the freezing point of the solution decreases to $1.86 \ K$. What is the value of $\Delta T_b$? $[K_f = 1.86, K_b = 0.512]$

$A$ cylinder containing an ideal gas ($0.1 \; mol$ in $1.0 \; dm^{3}$) is in thermal equilibrium with a large volume of $0.5 \; m$ (molal) aqueous solution of ethylene glycol at its freezing point. If the stoppers $S_{1}$ and $S_{2}$ (as shown in the figure) are suddenly withdrawn,the volume of the gas in litres after equilibrium is achieved will be ............ $litre$.
(Given: $K_{f}$ (water) $= 2.0 \; K \; kg \; mol^{-1}$,$R = 0.08 \; dm^{3} \; atm \; K^{-1} \; mol^{-1}$,freezing point of water $= 273 \; K$)