In a first-order reaction,the concentration of the reactant decreases from $0.80 \, mol \, L^{-1}$ to $0.06 \, mol \, L^{-1}$ in $45 \, min$. Calculate the half-life $(t_{1/2})$. (in $, min$)

For the gaseous reaction $A(g) \longrightarrow B(g) + C(g) + D(g)$,starting with an initial pressure of $400 \ atm$. If the total pressure after $2 \ hr$ is $800 \ atm$,the value of the rate constant is: (consider the reaction to be $1^{st}$ order): (in $hr^{-1}$)

For which of the following graphs is the intersection (y-intercept) zero?

$75\%$ of the first order reaction was completed in $32$ minutes. When was $50\%$ of the reaction completed? (in $\text{minutes}$)

For a first-order reaction involving gaseous reactants and gaseous products,what will be the unit of its rate constant?

$A$ first-order reaction decomposes such that the time taken for $1/8$ and $1/10$ of the initial concentration to decompose are $t_{1/8}$ and $t_{1/10}$ respectively. Find the value of $\frac{t_{1/8}}{t_{1/10}} \times 10$. (Given: $\log_{10} 2 = 0.3$)