In which of the following reactions is an alcohol formed as the major product?

  • A
    $ (CH_3)_3N \xrightarrow{NaNO_2 + HCl} $
  • B
    Aniline reacting with $NaNO_2 + HCl$ at $0-5^{\circ}C$
  • C
    Cyclopentyl-ethylamine reacting with $NaNO_2 + HCl$
  • D
    $N$-methylaniline reacting with $NaNO_2 + HCl$

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Arrange the following in increasing order of their basic strength:
$(i)$ $C_2H_5NH_2, C_6H_5NH_2, NH_3, C_6H_5CH_2NH_2$ and $(C_2H_5)_2NH$
$(ii)$ $C_2H_5NH_2, (C_2H_5)_2NH, (C_2H_5)_3N, C_6H_5NH_2$
$(iii)$ $CH_3NH_2, (CH_3)_2NH, (CH_3)_3N, C_6H_5NH_2, C_6H_5CH_2NH_2$

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Which of the following compounds gives an even number of Hoffmann's exhaustive methylation and elimination cycles?

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