Obtain the relation between specific heat capacity at constant pressure $(C_P)$ and specific heat capacity at constant volume $(C_V)$ for an ideal gas.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) For $1$ mole of an ideal gas,the first law of thermodynamics is $\Delta Q = \Delta U + \Delta W$.
At constant volume,$\Delta W = 0$,so $\Delta Q = \Delta U$. Since $\Delta U = C_V \Delta T$,we have $C_V = \frac{\Delta U}{\Delta T}$.
For an ideal gas,the internal energy $U$ depends only on temperature,so $\Delta U = C_V \Delta T$ holds for any process.
At constant pressure,$\Delta Q = \Delta U + P \Delta V$. Dividing by $\Delta T$,we get $\frac{\Delta Q}{\Delta T} = \frac{\Delta U}{\Delta T} + P \frac{\Delta V}{\Delta T}$.
This gives $C_P = C_V + P \frac{\Delta V}{\Delta T}$.
From the ideal gas equation for $1$ mole,$PV = RT$. Differentiating at constant pressure,$P \Delta V = R \Delta T$,which implies $P \frac{\Delta V}{\Delta T} = R$.
Substituting this into the expression for $C_P$,we get $C_P = C_V + R$.
Therefore,the relation is $C_P - C_V = R$.

Explore More

Similar Questions

For a gas,$\frac{R}{C_{v}} = 0.67$. This gas is made up of molecules which are

The amount of heat energy required to raise the temperature of $1\,g$ of helium from $T_1\,K$ to $T_2\,K$ is

Difficult
View Solution

$176 \text{ grams}$ of $CO_2$ can change its temperature from $0^{\circ} C$ to $30^{\circ} C$ by absorbing $3600 \text{ joules}$ of thermal energy. The molar specific heat of $CO_2$ in $J \ mol^{-1} K^{-1}$ is:

Which of the following formulae is wrong?

What is the correct relationship between molar specific heat at constant pressure $(C_P)$ and constant volume $(C_V)$? ($R$ is the universal gas constant)

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo