On the basis of crystal field theory,explain why $Co(III)$ forms a paramagnetic octahedral complex with weak field ligands,whereas it forms a diamagnetic octahedral complex with strong field ligands.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) $Co^{3+}$ has a $d^{6}$ electronic configuration.
In the presence of a strong field ligand,the crystal field splitting energy $\Delta_{o}$ is greater than the pairing energy $P$ (i.e.,$\Delta_{o} > P$). This forces the electrons to pair up in the lower energy $t_{2g}$ orbitals,resulting in a $t_{2g}^{6} e_{g}^{0}$ configuration.
Since all electrons are paired in the $t_{2g}^{6} e_{g}^{0}$ configuration,the complex is diamagnetic.
In the presence of a weak field ligand,$\Delta_{o} < P$. The electrons occupy the higher energy $e_{g}$ orbitals before pairing occurs,resulting in a $t_{2g}^{4} e_{g}^{2}$ configuration.
In the $t_{2g}^{4} e_{g}^{2}$ configuration,there are four unpaired electrons,making the complex paramagnetic.

Explore More

Similar Questions

The correct statements among $I$ to $III$ are:
$I$. Valence bond theory cannot explain the color exhibited by transition metal complexes.
$II$. Valence bond theory can predict quantitatively the magnetic properties of transition metal complexes.
$III$. Valence bond theory cannot distinguish ligands as weak and strong field ones.

The correct order for the wavelength of absorption in the visible region is

Which of the following produces high crystal field splitting?

Among the following pairs of complexes,in which case is the $\Delta_0$ value higher for the first one?

Assertion : Potassium ferrocyanide is diamagnetic,whereas potassium ferricyanide is paramagnetic.
Reason : Crystal field splitting in ferrocyanide ion is greater than that of ferricyanide ion.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo